Follow these steps to modify the SMTP settings in Outlook Express:
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Open Outlook Express.
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Click on Tools > Accounts > Mail Tab.
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Select the Account that needs to be changed.
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Click on Properties.
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In the Outgoing / SMTP Mail Server field, enter:
mail.your-domain-name.co.za
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Tick the option My server requires authentication.
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Under Settings, ensure that Use same settings as my incoming mail server is selected.
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Click OK, then Apply, and finally OK again.
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Click on Restart Outlook Express to apply the changes.
You have successfully updated your SMTP settings in Outlook Express!